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Accessing chiral sulfones bearing quaternary carbon stereocenters via photoinduced radical sulfur dioxide insertion and Truce–Smiles rearrangement

From the viewpoint of synthetic accessibility and functional group compatibility, photoredox-catalyzed sulfur dioxide insertion strategy enables in situ generation of functionalized sulfonyl radicals from easily accessible starting materials under mild conditions, thereby conferring broader applicat...

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Detalles Bibliográficos
Autores principales: Huang, Jiapian, Liu, Fei, Zeng, Ling-Hui, Li, Shaoyu, Chen, Zhiyuan, Wu, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9674831/
https://www.ncbi.nlm.nih.gov/pubmed/36400779
http://dx.doi.org/10.1038/s41467-022-34836-y