Intramolecular redox cyclization reaction access to cinnolines from 2-nitrobenzyl alcohol and benzylamine via intermediate 2-nitrosobenzaldehyde

A transition-metal-free intramolecular redox cyclization reaction for the synthesis of cinnolines has been developed from 2-nitrobenzyl alcohol and benzylamine. Mechanistic investigations disclosed the involvement of a key intramolecular redox reaction, followed by condensation, azo isomerization to...

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Detalles Bibliográficos
Autores principales: Sa, Yun, Cai, Mao-Xin, Lv, Xin, Wu, Ai-Bin, Shu, Wen-Ming, Yu, Wei-Chu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9677437/
https://www.ncbi.nlm.nih.gov/pubmed/36425163
http://dx.doi.org/10.1039/d2ra06523a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9677437/
https://www.ncbi.nlm.nih.gov/pubmed/36425163
http://dx.doi.org/10.1039/d2ra06523a

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