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A theory-driven synthesis of symmetric and unsymmetric 1,2-bis(diphenylphosphino)ethane analogues via radical difunctionalization of ethylene

1,2-Bis(diphenylphosphino)ethane (DPPE) and its synthetic analogues are important structural motifs in organic synthesis, particularly as diphosphine ligands with a C(2)-alkyl-linker chain. Since DPPE is known to bind to many metal centers in a bidentate fashion to stabilize the corresponding metal...

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Detalles Bibliográficos
Autores principales: Takano, Hideaki, Katsuyama, Hitomi, Hayashi, Hiroki, Kanna, Wataru, Harabuchi, Yu, Maeda, Satoshi, Mita, Tsuyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9678890/
https://www.ncbi.nlm.nih.gov/pubmed/36411284
http://dx.doi.org/10.1038/s41467-022-34546-5