Divergent and Synergistic Photocatalysis: Hydro- and Oxoalkylation of Vinyl Arenes for the Stereoselective Synthesis of Cyclopentanols via a Formal [4+1]-Annulation of 1,3-Dicarbonyls

[Image: see text] The controllable divergent reactivity of 1,3-dicarbonyls is described, which enables the efficient hydro- and oxoalkylation of vinyl arenes. Both reaction pathways are initiated through the formation of polarity-reversed C-centered-radical intermediates at the active methylene cent...

Descripción completa

Detalles Bibliográficos
Autores principales: Katta, Narenderreddy, Zhao, Quan-Qing, Mandal, Tirtha, Reiser, Oliver
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9680001/
https://www.ncbi.nlm.nih.gov/pubmed/36439036
http://dx.doi.org/10.1021/acscatal.2c04736

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9680001/
https://www.ncbi.nlm.nih.gov/pubmed/36439036
http://dx.doi.org/10.1021/acscatal.2c04736

Ejemplares similares