P–C, P–N, and M–N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles

[Image: see text] Reactions of the heterometallic MoRe complex [MoReCp(μ-PR*)(CO)(6)] and its MoMn analogue with some small molecules having N–N multiple bonds, such as diazoalkanes and organic azides, were investigated (R* = 2,4,6-C(6)H(2)(t)Bu(3)). Reactions with excess ethyl diazoacetate proceede...

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Detalles Bibliográficos
Autores principales: Alvarez, M. Angeles, Cuervo, Pablo M., García, M. Esther, Ruiz, Miguel A., Vega, Patricia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682477/
https://www.ncbi.nlm.nih.gov/pubmed/36350690
http://dx.doi.org/10.1021/acs.inorgchem.2c02720

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682477/
https://www.ncbi.nlm.nih.gov/pubmed/36350690
http://dx.doi.org/10.1021/acs.inorgchem.2c02720

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