Cargando…
P–C, P–N, and M–N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles
[Image: see text] Reactions of the heterometallic MoRe complex [MoReCp(μ-PR*)(CO)(6)] and its MoMn analogue with some small molecules having N–N multiple bonds, such as diazoalkanes and organic azides, were investigated (R* = 2,4,6-C(6)H(2)(t)Bu(3)). Reactions with excess ethyl diazoacetate proceede...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682477/ https://www.ncbi.nlm.nih.gov/pubmed/36350690 http://dx.doi.org/10.1021/acs.inorgchem.2c02720 |