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One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH(3))(6)](3+)

[Image: see text] Oxidation of [Re(NCCH(3))(6)](2+) with the thianthrene radical cation results in the formation of [Re(NCCH(3))(6)](3+), one of the very rare cases of a fully solvated +3 complex. It was fully characterized by spectroscopy and X-ray structure analysis. In contrast to its reduced ana...

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Detalles Bibliográficos
Autores principales: Bolliger, Robin, Blacque, Olivier, Braband, Henrik, Alberto, Roger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682483/
https://www.ncbi.nlm.nih.gov/pubmed/36169602
http://dx.doi.org/10.1021/acs.inorgchem.2c02056