A Combined Experimental and Theoretical Investigation of Oxidation Catalysis by cis-[V(IV)(O)(Cl/F)(N(4))](+) Species Mimicking the Active Center of Metal-Enzymes

[Image: see text] Reaction of V(IV)OCl(2) with the nonplanar tetradentate N(4) bis-quinoline ligands yielded four oxidovanadium(IV) compounds of the general formula cis-[V(IV)(O)(Cl)(N(4))]Cl. Sequential treatment of the two nonmethylated N(4) oxidovanadium(IV) compounds with KF and NaClO(4) resulte...

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Detalles Bibliográficos
Autores principales: Papanikolaou, Michael G., Simaioforidou, Anastasia V., Drouza, Chryssoula, Tsipis, Athanassios C., Miras, Haralampos N., Keramidas, Anastasios D., Louloudi, Maria, Kabanos, Themistoklis A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682486/
https://www.ncbi.nlm.nih.gov/pubmed/36357045
http://dx.doi.org/10.1021/acs.inorgchem.2c02526

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682486/
https://www.ncbi.nlm.nih.gov/pubmed/36357045
http://dx.doi.org/10.1021/acs.inorgchem.2c02526

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