Rh-catalyzed alkoxycarbonylation of unactivated alkyl chlorides

A general rhodium-catalyzed selective carbonylative coupling of unactivated alkyl chlorides with aliphatic alcohols or phenols to the corresponding esters is presented for the first time. Crucial for this transformation is the addition of sodium iodide, which provides in situ more active alkyl iodid...

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Detalles Bibliográficos
Autores principales: Wang, Peng, Wang, Yaxin, Neumann, Helfried, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682885/
https://www.ncbi.nlm.nih.gov/pubmed/36507181
http://dx.doi.org/10.1039/d2sc04103k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682885/
https://www.ncbi.nlm.nih.gov/pubmed/36507181
http://dx.doi.org/10.1039/d2sc04103k

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