Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out

The diphosphine complexes cis- or trans-[upper bond 1 start]PtCl(2)(P((CH(2))(n))(3)P[upper bond 1 end]) (n = b/12, c/14, d/16, e/18) are demetalated by MC[triple bond, length as m-dash]X nucleophiles to give the title compounds (P((CH(2))(n))(3))P (3b–e, 91–71%). These “empty cages” react with PdCl...

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Detalles Bibliográficos
Autores principales: Zhu, Yun, Stollenz, Michael, Zarcone, Samuel R., Kharel, Sugam, Joshi, Hemant, Bhuvanesh, Nattamai, Reibenspies, Joseph H., Gladysz, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682899/
https://www.ncbi.nlm.nih.gov/pubmed/36507162
http://dx.doi.org/10.1039/d2sc04724a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682899/
https://www.ncbi.nlm.nih.gov/pubmed/36507162
http://dx.doi.org/10.1039/d2sc04724a

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