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Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out
The diphosphine complexes cis- or trans-[upper bond 1 start]PtCl(2)(P((CH(2))(n))(3)P[upper bond 1 end]) (n = b/12, c/14, d/16, e/18) are demetalated by MC[triple bond, length as m-dash]X nucleophiles to give the title compounds (P((CH(2))(n))(3))P (3b–e, 91–71%). These “empty cages” react with PdCl...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682899/ https://www.ncbi.nlm.nih.gov/pubmed/36507162 http://dx.doi.org/10.1039/d2sc04724a |