Reassessment of N(2) activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N(2) adduct is actually an arene adduct

The complex {(TMEDA)(2)Li}{[Ti(N(TMS)(2))(2)](2)(μ-η(2):η(2)-N(2))(2)} (5-Li) is the only transition metal N(2) complex ever reported with two side-on N(2) adducts. In this report, the similarity of 5-Li to a new inverse sandwich toluene adduct {(PhMe)K}{[Ti(N(TMS)(2))(2)](2)(μ-PhMe)} (6-K) necessit...

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Detalles Bibliográficos
Autores principales: Huh, Daniel N., Koby, Ross F., Stuart, Zoe E., Dunscomb, Rachel J., Schley, Nathan D., Tonks, Ian A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682900/
https://www.ncbi.nlm.nih.gov/pubmed/36507167
http://dx.doi.org/10.1039/d2sc04368h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682900/
https://www.ncbi.nlm.nih.gov/pubmed/36507167
http://dx.doi.org/10.1039/d2sc04368h

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