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Reassessment of N(2) activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N(2) adduct is actually an arene adduct
The complex {(TMEDA)(2)Li}{[Ti(N(TMS)(2))(2)](2)(μ-η(2):η(2)-N(2))(2)} (5-Li) is the only transition metal N(2) complex ever reported with two side-on N(2) adducts. In this report, the similarity of 5-Li to a new inverse sandwich toluene adduct {(PhMe)K}{[Ti(N(TMS)(2))(2)](2)(μ-PhMe)} (6-K) necessit...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682900/ https://www.ncbi.nlm.nih.gov/pubmed/36507167 http://dx.doi.org/10.1039/d2sc04368h |