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Stereospecific Formation of the rctt Isomer of Bis-crown-Containing Cyclobutane upon [2 + 2] Photocycloaddition of an (18-Crown-6)stilbene Induced by Self-Assembly via Hydrogen Bonding

[Image: see text] The formation and the spectroscopic and structural properties of 1:1 and 2:1 (ligand-to-dication) complexes of an (18-crown-6)stilbene with ethane-1,2-diammonium diperchlorate in MeCN were studied by UV–vis and NMR spectroscopy and by density functional theory calculations. Prolong...

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Detalles Bibliográficos
Autores principales: Martyanov, Timofey P., Vorozhtsov, Artem P., Aleksandrova, Nadezhda A., Sulimenkov, Ilia V., Ushakov, Evgeny N., Gromov, Sergey P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9685742/
https://www.ncbi.nlm.nih.gov/pubmed/36440159
http://dx.doi.org/10.1021/acsomega.2c05295