Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN(3)P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism

Three molybdenum trihalogenido complexes supported by different PN(3)P pincer ligands were synthesized and investigated regarding their activity towards catalytic N(2)-to-NH(3) conversion. The highest yields were obtained with the H-PN(3)P(tBu) ligand. The corresponding Mo(V)-nitrido complex also sh...

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Detalles Bibliográficos
Autores principales: Bedbur, Katja, Stucke, Nadja, Liehrs, Lina, Krahmer, Jan, Tuczek, Felix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9692791/
https://www.ncbi.nlm.nih.gov/pubmed/36431964
http://dx.doi.org/10.3390/molecules27227843

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9692791/
https://www.ncbi.nlm.nih.gov/pubmed/36431964
http://dx.doi.org/10.3390/molecules27227843

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