Cargando…

Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN(3)P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism

Three molybdenum trihalogenido complexes supported by different PN(3)P pincer ligands were synthesized and investigated regarding their activity towards catalytic N(2)-to-NH(3) conversion. The highest yields were obtained with the H-PN(3)P(tBu) ligand. The corresponding Mo(V)-nitrido complex also sh...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bedbur, Katja, Stucke, Nadja, Liehrs, Lina, Krahmer, Jan, Tuczek, Felix
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9692791/ https://www.ncbi.nlm.nih.gov/pubmed/36431964 http://dx.doi.org/10.3390/molecules27227843

Ejemplares similares

Crystal structure of [{FeCl(3)}(2)(μ-PC(H)P)(2)] [PC(H)P = 1,3-bis(2-diphenylphosphanylethyl)-3H-imidazol-1-ium] with an unknown solvent
por: Stucke, Nadja, et al.
Publicado: (2018)

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
por: Kuriyama, Shogo, et al.
Publicado: (2016)

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia
por: Tanaka, Hiromasa, et al.
Publicado: (2014)

A Chatt‐Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia
por: Engesser, Tobias A., et al.
Publicado: (2020)

Structural diversity of halocarbonyl molybdenum and tungsten PNP pincer complexes through ligand modifications
por: de Aguiar, Sara R. M. M., et al.
Publicado: (2016)

[Bis(diphenylphosphino)methane-κ(2) P,P′][bis(diphenylphosphinomethyl)diethoxysilane-κ(2) P,P′]bis(dinitrogen)molybdenum(0) benzene 0.7-solvate
por: Klatt, Kristina, et al.
Publicado: (2008)

The role of oxygen and water on molybdenum nanoclusters for electro catalytic ammonia production
por: Howalt, Jakob G, et al.
Publicado: (2014)

Direct synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand
por: Itabashi, Takayuki, et al.
Publicado: (2022)

Nickel(II) carbonyl, ammonia, and acetonitrile complexes supported by a pyridine dipyrrolide pincer ligand
por: Dias, H. V. Rasika, et al.
Publicado: (2020)

Synthesis and Characterization of Hydrido Carbonyl Molybdenum and Tungsten PNP Pincer Complexes
por: Öztopcu, Özgür, et al.
Publicado: (2013)

Low-Valent Molybdenum PNP Pincer Complexes as Catalysts for the Semihydrogenation of Alkynes
por: Both, Niklas F., et al.
Publicado: (2022)

Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes
por: Rauch, Michael, et al.
Publicado: (2020)

Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides
por: Safronov, Sergey V., et al.
Publicado: (2020)

Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand
por: Khade, Rahul L., et al.
Publicado: (2015)

A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
por: Fernández-Buenestado, Marta, et al.
Publicado: (2023)

Synthesis of Tetrahydroquinolines via Borrowing Hydrogen Methodology Using a Manganese PN(3) Pincer Catalyst
por: Hofmann, Natalie, et al.
Publicado: (2020)

Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism
por: Leischner, Thomas, et al.
Publicado: (2019)

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As)
por: Oberdorf, Kai, et al.
Publicado: (2021)

Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation
por: Liang, Yaoyu, et al.
Publicado: (2022)

Chelating Phosphorus–An O, C, O‐Coordinating Pincer‐Type Ligand Coordinating P(III) and P(V) Centres
por: Gock, Michael, et al.
Publicado: (2022)

Synthesis and catalytic properties of a series of cobalt porphyrins as cytochrome P450 model: the effect of substituents on the catalytic activity
por: Hu, Bingcheng, et al.
Publicado: (2012)

[1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate)
por: Stephan, Gerald, et al.
Publicado: (2008)

New Molybdenum(II) Complexes with α-Diimine Ligands: Synthesis, Structure, and Catalytic Activity in Olefin Epoxidation
por: Vasconcellos-Dias, Maria, et al.
Publicado: (2019)

Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes
por: Pecak, Jan, et al.
Publicado: (2021)

Dehydropolymerization of H(3)B·NMeH(2) Mediated by Cationic Iridium(III) Precatalysts Bearing κ(3)-(i)Pr-PN(R)P Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism
por: Brodie, Claire N., et al.
Publicado: (2022)

Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes: Interplay between Water and Molecular Oxygen
por: de Aguiar, Sara R. M. M., et al.
Publicado: (2018)

Pd(II) Complexes with Pyridine Ligands: Substituent Effects on the NMR Data, Crystal Structures, and Catalytic Activity
por: Kurpik, Gracjan, et al.
Publicado: (2022)

Crystal structures of a novel NNN pincer ligand and its dinuclear titanium(IV) alkoxide pincer complex
por: Pedziwiatr, Jakub, et al.
Publicado: (2017)

Transfer hydrogenation of aldehydes catalyzed by silyl hydrido iron complexes bearing a [PSiP] pincer ligand
por: Zhang, Peng, et al.
Publicado: (2018)

A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle
por: Roffe, Gavin W., et al.
Publicado: (2016)

Synthesis, Characterization, and Catalytic Reactivity of {CoNO}(8) PCP Pincer Complexes
por: Pecak, Jan, et al.
Publicado: (2020)

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
por: Eizawa, Aya, et al.
Publicado: (2017)

Strange particle production in pp and pN reactions
por: Greiner, W, et al.
Publicado: (1984)

Dipyrromethane‐Based PGeP Pincer Germyl Rhodium Complexes
por: Cabeza, Javier A., et al.
Publicado: (2022)

The $C^{12}$(p,pn)$C^{11}$ and $Al^{27}$(p,3pn)$Na^{24}$ cross-sections at 591 MeV
por: Gobel, K, et al.
Publicado: (1961)

Peripheral pn production and decay angular distributions in the reaction pi /sup -/p to (pn)p at 12 GeV/c incident momentum
por: Ghidini, B, et al.
Publicado: (1978)

Highly Selective Molybdenum ONO Pincer Complex Initiates the Living Ring-Opening Metathesis Polymerization of Strained Alkynes with Exceptionally Low Polydispersity Indices
por: Bellone, Donatela E., et al.
Publicado: (2014)

Nickel–Alkyl Complexes with a Reactive PNC‐Pincer Ligand
por: Jongbloed, Linda S., et al.
Publicado: (2018)

Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand
por: Poole, Ethan W., et al.
Publicado: (2022)

Spin-spin correlations in the reaction p$^{-->}$p$^{-->}$ --> pn.pi+ at intermediate energies
por: Shypit, R L, et al.
Publicado: (1982)

Cannot write session to /tmp/vufind_sessions/sess_4a7fo2ktvnt589ps42v8ibaicp