Stereoselective Synthesis of Bisfuranoxide (Aurochrome, Auroxanthin) and Monofuranoxide (Equinenone 5′,8′-Epoxide) Carotenoids by Double Horner–Wadsworth–Emmons Reaction

[Image: see text] The stereoselective synthesis of C(40)-all-trans-carotenoids with the formal hexahydrobenzofuran skeletons aurochrome, auroxanthin, and equinenone-5′,8′-epoxide is reported. The synthesis is based on a one-pot or stepwise double Horner–Wadsworth–Emmons (HWE) reaction of a terminal...

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Detalles Bibliográficos
Autores principales: Rivas, Aurea, Castiñeira, Marta, Álvarez, Rosana, Vaz, Belén, de Lera, Angel R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society and American Society of Pharmacognosy 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9693700/
https://www.ncbi.nlm.nih.gov/pubmed/36121920
http://dx.doi.org/10.1021/acs.jnatprod.2c00475

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9693700/
https://www.ncbi.nlm.nih.gov/pubmed/36121920
http://dx.doi.org/10.1021/acs.jnatprod.2c00475

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