Unusual Effect of α-olefins as Chain Transfer Agents in Ethylene Polymerization over the Catalyst with Nonsymmetrical Bis(imino)pyridine Complex of Fe(II) and Modified Methylalumoxane (MMAO) Cocatalyst

Ethylene polymerization with bis(imino)pyridlyiron precatalysts generally produces linear polyethylene (PE) even with the presence of α-olefins because α-olefins are not incorporated into polymeric products. Interestingly, α-olefins, such as hexene-1 or butene-1, have been found to act as effective...

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Detalles Bibliográficos
Autores principales: Semikolenova, Nina V., Matsko, Mikhail A., Zakharov, Vladimir A., Sun, Wen-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9697923/
https://www.ncbi.nlm.nih.gov/pubmed/36430872
http://dx.doi.org/10.3390/ijms232214384

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9697923/
https://www.ncbi.nlm.nih.gov/pubmed/36430872
http://dx.doi.org/10.3390/ijms232214384

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