Synthesis and Characterisation of Novel Bis(diphenylphosphane oxide)methanidoytterbium(III) Complexes

Reaction of [YbCp(2)(dme)] (Cp = cyclopentadienyl, dme = 1,2 dimethoxyethane) with bis(diphenylphosphano)methane dioxide (H(2)dppmO(2)) leads to deprotonation of the ligand H(2)dppmO(2) and oxidation of ytterbium, forming an extremely air-sensitive product, [Yb(III)(HdppmO(2))(3)] (1), a six-coordin...

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Detalles Bibliográficos
Autores principales: Rangarajan, Shalini, Beaumont, Owen A., Balakrishna, Maravanji S., Deacon, Glen B., Blair, Victoria L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9698226/
https://www.ncbi.nlm.nih.gov/pubmed/36431801
http://dx.doi.org/10.3390/molecules27227704

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9698226/
https://www.ncbi.nlm.nih.gov/pubmed/36431801
http://dx.doi.org/10.3390/molecules27227704

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