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Total Synthesis of Loroxanthin
The first total synthesis of loroxanthin (1) was accomplished by Horner-Wadsworth-Emmons reaction of C(25)-apocarotenal 8 having a silyl-protected 19-hydroxy moiety with C(15)-phosphonate 25 bearing a silyl-protected 3-hydroxy-ε-end group. Preparation of apocarotenal 8 was achieved via Stille coupli...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9699617/ https://www.ncbi.nlm.nih.gov/pubmed/36354981 http://dx.doi.org/10.3390/md20110658 |