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Total Synthesis of Loroxanthin

The first total synthesis of loroxanthin (1) was accomplished by Horner-Wadsworth-Emmons reaction of C(25)-apocarotenal 8 having a silyl-protected 19-hydroxy moiety with C(15)-phosphonate 25 bearing a silyl-protected 3-hydroxy-ε-end group. Preparation of apocarotenal 8 was achieved via Stille coupli...

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Detalles Bibliográficos
Autores principales:	Yamano, Yumiko, Tanabe, Mari, Shimada, Atsushi, Wada, Akimori
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9699617/ https://www.ncbi.nlm.nih.gov/pubmed/36354981 http://dx.doi.org/10.3390/md20110658

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