How mono- and diphosphine ligands alter regioselectivity of the Rh-catalyzed annulative cleavage of bicyclo[1.1.0]butanes

Rh(I)-catalyzed cycloisomerizations of bicyclo[1.1.0]butanes provide a fruitful approach to cyclopropane-fused heterocycles. Products and stereochemical outcome are highly dependent on catalyst. The triphenylphosphine (PPh(3)) ligand provides pyrrolidines, placing substituents anti to the cyclopropy...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Pan-Pan, Wipf, Peter, Houk, K. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9701199/
https://www.ncbi.nlm.nih.gov/pubmed/36435835
http://dx.doi.org/10.1038/s41467-022-34837-x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9701199/
https://www.ncbi.nlm.nih.gov/pubmed/36435835
http://dx.doi.org/10.1038/s41467-022-34837-x

Ejemplares similares