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How mono- and diphosphine ligands alter regioselectivity of the Rh-catalyzed annulative cleavage of bicyclo[1.1.0]butanes

Rh(I)-catalyzed cycloisomerizations of bicyclo[1.1.0]butanes provide a fruitful approach to cyclopropane-fused heterocycles. Products and stereochemical outcome are highly dependent on catalyst. The triphenylphosphine (PPh(3)) ligand provides pyrrolidines, placing substituents anti to the cyclopropy...

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Detalles Bibliográficos
Autores principales:	Chen, Pan-Pan, Wipf, Peter, Houk, K. N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9701199/ https://www.ncbi.nlm.nih.gov/pubmed/36435835 http://dx.doi.org/10.1038/s41467-022-34837-x

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