A Zintl Cluster for Transition Metal-Free Catalysis: C=O Bond Reductions

[Image: see text] The first fully characterized boron-functionalized heptaphosphide Zintl cluster, [(BBN)P(7)](2–) ([1](2–)), is synthesized by dehydrocoupling [HP(7)](2–). Dehydrocoupling is a previously unprecedented reaction pathway to functionalize Zintl clusters. [Na(18-c-6)](2)[1] was employed...

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Detalles Bibliográficos
Autores principales: van IJzendoorn, Bono, Albawardi, Saad F., Vitorica-Yrezabal, Inigo J., Whitehead, George F. S., McGrady, John E., Mehta, Meera
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706568/
https://www.ncbi.nlm.nih.gov/pubmed/36351036
http://dx.doi.org/10.1021/jacs.2c08559

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706568/
https://www.ncbi.nlm.nih.gov/pubmed/36351036
http://dx.doi.org/10.1021/jacs.2c08559

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