Cargando…
A Zintl Cluster for Transition Metal-Free Catalysis: C=O Bond Reductions
[Image: see text] The first fully characterized boron-functionalized heptaphosphide Zintl cluster, [(BBN)P(7)](2–) ([1](2–)), is synthesized by dehydrocoupling [HP(7)](2–). Dehydrocoupling is a previously unprecedented reaction pathway to functionalize Zintl clusters. [Na(18-c-6)](2)[1] was employed...
Autores principales: | van IJzendoorn, Bono, Albawardi, Saad F., Vitorica-Yrezabal, Inigo J., Whitehead, George F. S., McGrady, John E., Mehta, Meera |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706568/ https://www.ncbi.nlm.nih.gov/pubmed/36351036 http://dx.doi.org/10.1021/jacs.2c08559 |
Ejemplares similares
-
Heteroallene Capture and Exchange at Functionalised Heptaphosphane Clusters
por: van IJzendoorn, Bono, et al.
Publicado: (2021) -
Missing
Link in the Growth of Lead-Based Zintl Clusters:
Isolation of the Dimeric Plumbaspherene [Cu(4)Pb(22)](4–)
por: Morgan, Harry W. T., et al.
Publicado: (2022) -
A Neutral
Heteroatomic Zintl Cluster for the Catalytic
Hydrogenation of Cyclic Alkenes
por: Townrow, Oliver P. E., et al.
Publicado: (2020) -
Tying
a Molecular Overhand Knot of Single Handedness
and Asymmetric Catalysis with the Corresponding Pseudo-D(3)-Symmetric Trefoil Knot
por: Gil-Ramírez, Guzmán, et al.
Publicado: (2016) -
Special Issue: Advances in Zintl Phases
por: Kauzlarich, Susan M.
Publicado: (2019)