Enantioselective Intramolecular Iridium-Catalyzed Cyclopropanation of α-Carbonyl Sulfoxonium Ylides

[Image: see text] Enantioselective cyclopropanation of α-carbonyl sulfoxonium ylides (SY) has so far been limited to addition/ring closure reactions on electron-poor olefins. Herein, we report the iridium-catalyzed intramolecular cyclopropanation of SY in the presence of a chiral diene in up to 96%...

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Detalles Bibliográficos
Autores principales: Vidal, Lucas, Chen, Pan-Pan, Nicolas, Eva, Hackett, Andrew, Robertson, Craig M., Houk, Kendall N., Aïssa, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706811/
https://www.ncbi.nlm.nih.gov/pubmed/36367970
http://dx.doi.org/10.1021/acs.orglett.2c03396

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706811/
https://www.ncbi.nlm.nih.gov/pubmed/36367970
http://dx.doi.org/10.1021/acs.orglett.2c03396

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