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Enantioselective Intramolecular Iridium-Catalyzed Cyclopropanation of α-Carbonyl Sulfoxonium Ylides

[Image: see text] Enantioselective cyclopropanation of α-carbonyl sulfoxonium ylides (SY) has so far been limited to addition/ring closure reactions on electron-poor olefins. Herein, we report the iridium-catalyzed intramolecular cyclopropanation of SY in the presence of a chiral diene in up to 96%...

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Detalles Bibliográficos
Autores principales:	Vidal, Lucas, Chen, Pan-Pan, Nicolas, Eva, Hackett, Andrew, Robertson, Craig M., Houk, Kendall N., Aïssa, Christophe
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706811/ https://www.ncbi.nlm.nih.gov/pubmed/36367970 http://dx.doi.org/10.1021/acs.orglett.2c03396

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