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Mechanistic insights into reductive deamination with hydrosilanes catalyzed by B(C(6)F(5))(3): A DFT study

Selective defunctionalization of synthetic intermediates is a valuable approach in organic synthesis. Here, we present a theoretical study on the recently developed B(C(6)F(5))(3)/hydrosilane-mediated reductive deamination reaction of primary amines. Our computational results provide important insig...

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Detalles Bibliográficos
Autores principales: Zhou, Miaomiao, Wang, Ting, Cheng, Gui-Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9709212/
https://www.ncbi.nlm.nih.gov/pubmed/36465875
http://dx.doi.org/10.3389/fchem.2022.1025135