Cargando…
Mechanistic insights into reductive deamination with hydrosilanes catalyzed by B(C(6)F(5))(3): A DFT study
Selective defunctionalization of synthetic intermediates is a valuable approach in organic synthesis. Here, we present a theoretical study on the recently developed B(C(6)F(5))(3)/hydrosilane-mediated reductive deamination reaction of primary amines. Our computational results provide important insig...
Autores principales: | Zhou, Miaomiao, Wang, Ting, Cheng, Gui-Juan |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9709212/ https://www.ncbi.nlm.nih.gov/pubmed/36465875 http://dx.doi.org/10.3389/fchem.2022.1025135 |
Ejemplares similares
-
Reductive Deamination with Hydrosilanes Catalyzed by B(C(6)F(5))(3)
por: Fang, Huaquan, et al.
Publicado: (2020) -
Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO(2) with hydrosilanes
por: Guzmán, Jefferson, et al.
Publicado: (2020) -
Palladium-catalyzed tandem allylic substitution/cyclization and cascade hydrosilylated reduction: the influence of reaction parameters and hydrosilanes on the stereoselectivity
por: Long, Peng-Wei, et al.
Publicado: (2018) -
Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
por: Chen, Yi, et al.
Publicado: (2020) -
Mechanistic insight into B(C(6)F(5))(3) catalyzed imine reduction with PhSiH(3) under stoichiometric water conditions
por: He, Yunqing, et al.
Publicado: (2021)