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Catalytic Cyanation of C–N Bonds with CO(2)/NH(3)
[Image: see text] Cyanation of benzylic C–N bonds is useful in the preparation of important α-aryl nitriles. The first general catalytic cyanation of α-(hetero)aryl amines, analogous to the Sandmeyer reaction of anilines, was developed using reductive cyanation with CO(2)/NH(3). A broad array of α-a...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9709945/ https://www.ncbi.nlm.nih.gov/pubmed/36465537 http://dx.doi.org/10.1021/jacsau.2c00392 |