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Taming Highly Unstable Radical Anions and 1,4-Organodilithiums by Flow Microreactors: Controlled Reductive Dimerization of Styrenes

[Image: see text] The reduction of styrenes with lithium arenide in a flow microreactor leads to the instantaneous generation of highly unstable radical anions that subsequently dimerize to yield the corresponding 1,4-organodilithiums. A flow reactor with fast mixing is essential for this reductive...

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Detalles Bibliográficos
Autores principales: Jiang, Yiyuan, Yorimitsu, Hideki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9709950/
https://www.ncbi.nlm.nih.gov/pubmed/36465543
http://dx.doi.org/10.1021/jacsau.2c00375