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Supervalence Bonding in Bi-icosahedral Cores of [M(1)Au(37)(SC(2)H(4)Ph)(24)](−) (M = Pd and Pt): Fusion-Mediated Synthesis and Anion Photoelectron Spectroscopy
[Image: see text] Au(38)(PET)(24) (PET = SC(2)H(4)Ph) is known to have a bi-icosahedral Au(23) core consisting of two Au(13) icosahedrons by sharing three Au atoms. Previous theoretical studies based on a supervalence bond (SVB) model have demonstrated that the bonding scheme in the Au(23) core is s...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9709954/ https://www.ncbi.nlm.nih.gov/pubmed/36465538 http://dx.doi.org/10.1021/jacsau.2c00519 |