Iridium-catalyzed enantioselective alkynylation and kinetic resolution of alkyl allylic alcohols

Herein, we report an efficient kinetic resolution of alkyl allylic alcohols enabled by an iridium-catalyzed enantioselective alkynylation of alkyl allylic alcohols with potassium alkynyltrifluoroborates. A wide range of chiral 1,4-enynes bearing various functional groups and unreacted enantioenriche...

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Detalles Bibliográficos
Autores principales: Guo, Jia, Ma, Hao-Ran, Xiong, Wen-Bin, Fan, Luoyi, Zhou, You-Yun, Wong, Henry N. C., Cui, Jian-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710208/
https://www.ncbi.nlm.nih.gov/pubmed/36544735
http://dx.doi.org/10.1039/d2sc04892b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710208/
https://www.ncbi.nlm.nih.gov/pubmed/36544735
http://dx.doi.org/10.1039/d2sc04892b

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