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Multiple remote C(sp(3))–H functionalizations of aliphatic ketones via bimetallic Cu–Pd catalyzed successive dehydrogenation

The dehydrogenation-triggered multiple C(sp(3))–H functionalizations at remote positions γ, δ or ε, ζ to carbonyl groups of aliphatic ketones with aryl/alkenyl carboxylic acids as coupling partners have been achieved using a bimetallic Cu–Pd catalyst system. This reaction allows access to alkenylate...

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Detalles Bibliográficos
Autores principales: Li, Hongyi, Yin, Chang, Liu, Sien, Tu, Hua, Lin, Ping, Chen, Jing, Su, Weiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710215/
https://www.ncbi.nlm.nih.gov/pubmed/36544736
http://dx.doi.org/10.1039/d2sc05370e