Cargando…
Uranium(iv) alkyl cations: synthesis, structures, comparison with thorium(iv) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity
Reaction of [(XA(2))U(CH(2)SiMe(3))(2)] (1; XA(2) = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) with 1 equivalent of [Ph(3)C][B(C(6)F(5))(4)] in arene solvents afforded the arene-coordinated uranium alkyl cations, [(XA(2))U(CH(2)SiMe(3))(η(n)-arene)][B(C(6)F(5))(4)] {aren...
Autores principales: | , , , , , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710223/ https://www.ncbi.nlm.nih.gov/pubmed/36544741 http://dx.doi.org/10.1039/d2sc04302e |