Uranium(iv) alkyl cations: synthesis, structures, comparison with thorium(iv) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity

Reaction of [(XA(2))U(CH(2)SiMe(3))(2)] (1; XA(2) = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) with 1 equivalent of [Ph(3)C][B(C(6)F(5))(4)] in arene solvents afforded the arene-coordinated uranium alkyl cations, [(XA(2))U(CH(2)SiMe(3))(η(n)-arene)][B(C(6)F(5))(4)] {aren...

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Detalles Bibliográficos
Autores principales: Andreychuk, Nicholas R., Vidjayacoumar, Balamurugan, Price, Jeffrey S., Kervazo, Sophie, Peeples, Craig A., Emslie, David J. H., Vallet, Valérie, Gomes, André S. P., Réal, Florent, Schreckenbach, Georg, Ayers, Paul W., Vargas-Baca, Ignacio, Jenkins, Hilary A., Britten, James F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710223/
https://www.ncbi.nlm.nih.gov/pubmed/36544741
http://dx.doi.org/10.1039/d2sc04302e

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