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InI(3)-catalyzed polyene cyclization of allenes and its application in the total synthesis of seven abietane-type diterpenoids

A novel polyene cyclization using the allene group as the initiator has been successfully developed. This methodology provides an efficient strategy for the construction of an abietane-type tricyclic skeleton with a functionalizable C2–C3 double bond and features a wide substrate scope and excellent...

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Detalles Bibliográficos
Autores principales: Huo, Chen-Yu, Zheng, Tian-Lu, Dai, Wei-Hao, Zhang, Zi-Hao, Wang, Jin-Da, Zhu, Dao-Yong, Wang, Shao-Hua, Zhang, Xiao-Ming, Xu, Xue-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710309/
https://www.ncbi.nlm.nih.gov/pubmed/36544726
http://dx.doi.org/10.1039/d2sc04229k