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InI(3)-catalyzed polyene cyclization of allenes and its application in the total synthesis of seven abietane-type diterpenoids
A novel polyene cyclization using the allene group as the initiator has been successfully developed. This methodology provides an efficient strategy for the construction of an abietane-type tricyclic skeleton with a functionalizable C2–C3 double bond and features a wide substrate scope and excellent...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710309/ https://www.ncbi.nlm.nih.gov/pubmed/36544726 http://dx.doi.org/10.1039/d2sc04229k |