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Iridium(I)– and Rhodium(I)–Olefin Complexes Containing an α-Diimine Supporting Ligand

[Image: see text] Iridium(I) complexes of the type IrX(olefin)(α-diimine) (α-diimine = 1,4-bis(2,6-xylyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; X = Cl, I, Me, O(2)CCF(3); olefin = ethylene, cyclooctene (COE)) were synthesized from the readily available precursor [IrCl(COE)(2)](2). These complexes di...

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Detalles Bibliográficos
Autores principales: Kovach, James, Golisz, Suzanne R., Brennessel, William W., Jones, William D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710518/
https://www.ncbi.nlm.nih.gov/pubmed/36466792
http://dx.doi.org/10.1021/acs.organomet.2c00036