Synthesis of chiral-at-metal rhodium complexes from achiral tripodal tetradentate ligands: resolution and application to enantioselective Diels–Alder and 1,3-dipolar cycloadditions

An improved synthesis of the racemic rhodium compound [RhCl(2)(κ(4)C,N,N′,P-L1)] (1) containing an achiral tripodal tetradentate ligand is reported. Their derived solvate complexes [Rh(κ(4)C,N,N′,P-L1)(Solv)(2)][SbF(6)](2) (Solv = NCMe, 2; H(2)O, 3) are resolved into their two enantiomers. Complexes...

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Detalles Bibliográficos
Autores principales: Tejero, Alvaro G., Carmona, María, Rodríguez, Ricardo, Viguri, Fernando, Lahoz, Fernando J., García-Orduña, Pilar, Carmona, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9717581/
https://www.ncbi.nlm.nih.gov/pubmed/36545596
http://dx.doi.org/10.1039/d2ra06982b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9717581/
https://www.ncbi.nlm.nih.gov/pubmed/36545596
http://dx.doi.org/10.1039/d2ra06982b

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