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Synthesis of chiral-at-metal rhodium complexes from achiral tripodal tetradentate ligands: resolution and application to enantioselective Diels–Alder and 1,3-dipolar cycloadditions
An improved synthesis of the racemic rhodium compound [RhCl(2)(κ(4)C,N,N′,P-L1)] (1) containing an achiral tripodal tetradentate ligand is reported. Their derived solvate complexes [Rh(κ(4)C,N,N′,P-L1)(Solv)(2)][SbF(6)](2) (Solv = NCMe, 2; H(2)O, 3) are resolved into their two enantiomers. Complexes...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9717581/ https://www.ncbi.nlm.nih.gov/pubmed/36545596 http://dx.doi.org/10.1039/d2ra06982b |