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One-Pot Synthesis of Styrene Derivatives from Allyl Silanes via B(C(6)F(5))(3)-Catalyzed Isomerization–Hiyama Coupling

[Image: see text] Herein, we report a one-pot synthesis of styrene derivatives via a novel B(C(6)F(5))(3)-catalyzed E-selective isomerization of readily accessible allyl silanes and subsequent Hiyama coupling of the versatile alkenyl silane intermediates. This one-pot, two-step approach enables acce...

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Detalles Bibliográficos
Autores principales: Kustiana, Betty A., Melen, Rebecca L., Morrill, Louis C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9724089/
https://www.ncbi.nlm.nih.gov/pubmed/36394303
http://dx.doi.org/10.1021/acs.orglett.2c03584