Palladium-Catalyzed Ortho C–H Arylation of Unprotected Anilines: Chemo- and Regioselectivity Enabled by the Cooperating Ligand [2,2′-Bipyridin]-6(1H)-one

[Image: see text] Metal-catalyzed C–H functionalizations on the aryl ring of anilines usually need cumbersome N-protection–deprotection strategies to ensure chemoselectivity. We describe here the Pd-catalyzed direct C–H arylation of unprotected anilines with no competition of the N-arylation product...

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Detalles Bibliográficos
Autores principales: Pinilla, Cintya, Salamanca, Vanesa, Lledós, Agustí, Albéniz, Ana C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9724229/
https://www.ncbi.nlm.nih.gov/pubmed/36504914
http://dx.doi.org/10.1021/acscatal.2c05206

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9724229/
https://www.ncbi.nlm.nih.gov/pubmed/36504914
http://dx.doi.org/10.1021/acscatal.2c05206

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