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Potential- and Buffer-Dependent Selectivity for the Conversion of CO(2) to CO by a Cobalt Porphyrin-Peptide Electrocatalyst in Water

[Image: see text] A semisynthetic electrocatalyst for carbon dioxide reduction to carbon monoxide in water is reported. Cobalt microperoxidase-11 (CoMP11-Ac) is shown to reduce CO(2) to CO with a turnover number of up to 32,000 and a selectivity of up to 88:5 CO:H(2). Higher selectivity for CO produ...

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Detalles Bibliográficos
Autores principales: Alvarez-Hernandez, Jose L., Salamatian, Alison A., Han, Ji Won, Bren, Kara L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9724230/
https://www.ncbi.nlm.nih.gov/pubmed/36504916
http://dx.doi.org/10.1021/acscatal.2c03297