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Potential- and Buffer-Dependent Selectivity for the Conversion of CO(2) to CO by a Cobalt Porphyrin-Peptide Electrocatalyst in Water
[Image: see text] A semisynthetic electrocatalyst for carbon dioxide reduction to carbon monoxide in water is reported. Cobalt microperoxidase-11 (CoMP11-Ac) is shown to reduce CO(2) to CO with a turnover number of up to 32,000 and a selectivity of up to 88:5 CO:H(2). Higher selectivity for CO produ...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9724230/ https://www.ncbi.nlm.nih.gov/pubmed/36504916 http://dx.doi.org/10.1021/acscatal.2c03297 |