Controlled monodefluorination and alkylation of C(sp(3))–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity

The controlled functionalization of a single fluorine in a CF(3) group is difficult and rare. Photochemical C–F bond functionalization of the sp(3)-C–H bond in trifluorotoluene, PhCF(3), is achieved using catalysts made from earth-abundant lanthanides, (Cp(Me4))(2)Ln(2-O-3,5-(t)Bu(2)-C(6)H(2))(1-C{N...

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Detalles Bibliográficos
Autores principales: Kynman, Amy E., Elghanayan, Luca K., Desnoyer, Addison N., Yang, Yan, Sévery, Laurent, Di Giuseppe, Andrea, Tilley, T. Don, Maron, Laurent, Arnold, Polly L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728647/
https://www.ncbi.nlm.nih.gov/pubmed/36540817
http://dx.doi.org/10.1039/d2sc04192h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728647/
https://www.ncbi.nlm.nih.gov/pubmed/36540817
http://dx.doi.org/10.1039/d2sc04192h

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