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Enhanced Adsorption Selectivity of Carbon Dioxide and Ethane on Porous Metal–Organic Framework Functionalized by a Sulfur-Rich Heterocycle

Porous metal–organic framework [Zn(2)(ttdc)(2)(bpy)] (1) based on thieno [3,2-b]thiophenedicarboxylate (ttdc) was synthesized and characterized. The structure contains intersected zig-zag channels with an average aperture of 4 × 6 Å and a 49% (v/v) guest-accessible pore volume. Gas adsorption studie...

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Detalles Bibliográficos
Autores principales: Dubskikh, Vadim A., Kovalenko, Konstantin A., Nizovtsev, Anton S., Lysova, Anna A., Samsonenko, Denis G., Dybtsev, Danil N., Fedin, Vladimir P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9737143/
https://www.ncbi.nlm.nih.gov/pubmed/36500905
http://dx.doi.org/10.3390/nano12234281