The Origin of Stereoselectivity in the Hydrogenation of Oximes Catalyzed by Iridium Complexes: A DFT Mechanistic Study

Herein the reaction mechanism and the origin of stereoselectivity of asymmetric hydrogenation of oximes to hydroxylamines catalyzed by the cyclometalated iridium (III) complexes with chiral substituted single cyclopentadienyl ligands (Ir catalysts A1 and B1) under acidic condition were unveiled usin...

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Detalles Bibliográficos
Autores principales: Ali, Qaim, Chen, Yongyong, Zhang, Ruixue, Li, Zhewei, Tang, Yanhui, Pu, Min, Lei, Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9737400/
https://www.ncbi.nlm.nih.gov/pubmed/36500448
http://dx.doi.org/10.3390/molecules27238349

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9737400/
https://www.ncbi.nlm.nih.gov/pubmed/36500448
http://dx.doi.org/10.3390/molecules27238349

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