Nucleophilic Substitution at Tricoordinate Sulfur—Alkaline Hydrolysis of Optically Active Dialkoxysulfonium Salts: Stereochemistry, Mechanism and Reaction Energetics

Optically active dialkoxyisopropylsulfonium salts were obtained by methylation (ethylation) of optically active alkyl isopropanesulfinates using methyl (ethyl) trifluoromethanesulfonate. Alkaline hydrolysis of a series of methoxy(alkoxy)sulfonium salts afforded the two sulfinate products methyl isop...

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Detalles Bibliográficos
Autores principales: Mikołajczyk, Marian, Bujnicki, Bogdan, Drabowicz, Józef, Cypryk, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9739154/
https://www.ncbi.nlm.nih.gov/pubmed/36500306
http://dx.doi.org/10.3390/molecules27238212

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9739154/
https://www.ncbi.nlm.nih.gov/pubmed/36500306
http://dx.doi.org/10.3390/molecules27238212

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