Hybrid Silsesquioxane/Benzoate Cu(7)-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity

A series of phenylsilsesquioxane-benzoate heptacopper complexes 1–3 were synthesized and characterized by X-ray crystallography. Two parallel routes of toluene spontaneous oxidation (into benzyl alcohol and benzoate) assisted the formation of the cagelike structure 1. A unique multi-ligation of copp...

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Detalles Bibliográficos
Autores principales: Bilyachenko, Alexey N., Khrustalev, Victor N., Gutsul, Evgenii I., Zueva, Anna Y., Korlyukov, Alexander A., Shul’pina, Lidia S., Ikonnikov, Nikolay S., Dorovatovskii, Pavel V., Gelman, Dmitri, Shubina, Elena S., Shul’pin, Georgiy B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9739484/
https://www.ncbi.nlm.nih.gov/pubmed/36500598
http://dx.doi.org/10.3390/molecules27238505

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9739484/
https://www.ncbi.nlm.nih.gov/pubmed/36500598
http://dx.doi.org/10.3390/molecules27238505

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